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Qaagi - Book of Why

Causes

Effects

the coke formation which is believedto leadto catalyst deactivation

Coke formation on the catalystcausescatalyst deactivation

besides the coke formationmight contributeto catalyst deactivation

about 1500 � F. Such high temperatures in the dilute catalyst phasecan causedeactivation of the catalyst

catalyst sintering and carbon formationleadingto catalyst deactivation

Refereed ) Production of synthesis gas by catalytic reforming of product gas from biomass gasificationcan leadto catalyst deactivation

TIPB(passive) caused byalkylation catalyst deactivation

the yield of hydrocarbons ... coke formationresultsin catalyst deactivation

propane ... catalytic coke formationcausedcatalyst deactivation

both coke formation and metals deposition(passive) is caused byCatalyst deactivation

p.2481 - 2488 Production of synthesis gas by catalytic reforming of product gas from biomass gasificationcan leadto catalyst deactivation

carbon formation and maximizing the yield of hydrogen product(passive) caused bycatalyst deactivation

oxidation of the catalytically active Ir sites at high temperatures(passive) caused bycatalyst deactivation

to suppress coke accumulation ( mainly from polycyclic aromatic hydrocarbonsleadingto catalyst deactivation

p]Pure dry reactants are neededto preventcatalyst deactivation

the main reason ... likelyto causedeactivation of the catalyst

coke deposition in the mild stage(passive) caused bycatalyst deactivation

coke deposition and/or metal sintering(passive) was caused bythe catalyst deactivation

particular sulfur compounds and(passive) caused bycatalyst deactivation

any carbon deposits on the catalystswould ... causecatalyst deactivation

undesired side reactionsleadingto catalyst deactivation

catalyst contamination from a freshly metal - coated reactor systemwould ... resultin catalyst deactivation

the effectiveness factors for the CO2 molecule are higher than the O2 molecule and at high temperatures.000 Kleadingto catalyst deactivation

65500 kPa)/5500 � F. ( 260 � C. ) reactor , is performed inside a N2 filled drybox ( O2 less than 10 ppmto preventdeactivation of the catalyst

sintering and carbon deposition(passive) caused bycatalyst deactivation

the phenomenaleadto catalyst deactivation

sustained high temperature operationcan causecatalyst deactivation

The heavier portion ( molecular mass > 1,000 ... the coke formation and accumulationcausedthe catalyst deactivation

Jun 2 , 1992Mar 15 , 1994Chevron Research And Technology CompanyProcessto preventcatalyst deactivation

higher activity and selectivity than that of Pt / SrX.it ... coke depositsleadsto catalyst deactivation

They also act as coke precursorsleadingto catalyst deactivation

coke generation , etc(passive) caused bycatalyst deactivation

treating heavy oilsUS52981522 Jun 199229 Mar 1994Chevron Research And Technology CompanyProcessto preventcatalyst deactivation in

b ) Coking and fouling propensityresultsin catalyst deactivation

Rh segregation at the surface ... resulting from the volatilisation of Pt oxide at high temperatures after the oxidation of Rh and Pt(passive) may be caused bycatalyst deactivation

sulfur poisoning , in high concentrations(passive) caused bycatalyst deactivation

the main pollutantsleadingto catalyst deactivation

most catalyst lifetimes ... side reactionsleadto catalyst deactivation

In usual commercial use , these catalysts become fouled with metal contaminants and coke formationleadingto catalyst deactivation

that dehydration processes are too fast compared to H2 formation reactions at higher temperaturesleadingto catalyst deactivation

furfural conversion(passive) caused byfurfural conversion

from coke deposition on the catalyst surfacesresultingfrom coke deposition on the catalyst surfaces

to higher conversion and longer operating timeleadingto higher conversion and longer operating time

from polyalkylation of aromatics ... perhaps with a minor contribution from oligomerization , especially where the propylene concentration is quite largeresultedfrom polyalkylation of aromatics ... perhaps with a minor contribution from oligomerization , especially where the propylene concentration is quite large

from use in eliminating oxides of nitrogen from gases EP0071397B1 ( enresultingfrom use in eliminating oxides of nitrogen from gases EP0071397B1 ( en

declining reaction rates and higher reactor occupancy with an increasing number of catalyst recycleswill causedeclining reaction rates and higher reactor occupancy with an increasing number of catalyst recycles

periodic regeneration(passive) caused byperiodic regeneration

to catalyst lossesleadsto catalyst losses

by performing the process in two stepscan be preventedby performing the process in two steps

from the decomposition of zinc titanates , which are active componentsresultedfrom the decomposition of zinc titanates , which are active components

to the termination of CNT growthleadsto the termination of CNT growth

to loss of stabilityleadto loss of stability

A decreasing activity as a function of time on stream at constant operating conditions(passive) is then caused byA decreasing activity as a function of time on stream at constant operating conditions

from carbon laydownresultingfrom carbon laydown

from steaming during regenerationresultingfrom steaming during regeneration

to the reduction of byproduct reactionsleadsto the reduction of byproduct reactions

further accumulation of carbon along the bedpreventsfurther accumulation of carbon along the bed

by tuning the ligand / Rh ratiocould be preventedby tuning the ligand / Rh ratio

to the loss of activity , XRD , TEM and thermogravimetry and differential thermogravimetryleadingto the loss of activity , XRD , TEM and thermogravimetry and differential thermogravimetry

4 , 7 , 8leads4 , 7 , 8

in a short catalyst lifetimeresultsin a short catalyst lifetime

to catalyst inhibition and deactivationleadto catalyst inhibition and deactivation

incomplete conversions in some cases and therefore no unique set of reaction conditions with broad scope could be identifiedcausedincomplete conversions in some cases and therefore no unique set of reaction conditions with broad scope could be identified

from the differing treatment as shown in EXAMPLE 5resultingfrom the differing treatment as shown in EXAMPLE 5

from the deposition of coke within the zeolite pores , which restricted access of the reactants to the BrCnsted acid sitesresultedfrom the deposition of coke within the zeolite pores , which restricted access of the reactants to the BrCnsted acid sites

to useful catalyst lifetimes on the order of only several hoursleadingto useful catalyst lifetimes on the order of only several hours

in little product yielddeviationresultingin little product yielddeviation

from a strong but slow chemical interaction between the Mn - O bond and sulfur dioxideresultedfrom a strong but slow chemical interaction between the Mn - O bond and sulfur dioxide

to the moving of the operating pointleadsto the moving of the operating point

from destruction of at least one of the two essential components of the catalyst described abovepresumably resultsfrom destruction of at least one of the two essential components of the catalyst described above

in increased catalyst usage and/or less effective hydrogenationresultingin increased catalyst usage and/or less effective hydrogenation

in little product yield deviationresultingin little product yield deviation

in a decrease of yield of p - xylene with time on stream as shown in Tables 1 - 7resultedin a decrease of yield of p - xylene with time on stream as shown in Tables 1 - 7

The base line experiments at(passive) is caused byThe base line experiments at

to lesser amount of reaction over the bedcontributedto lesser amount of reaction over the bed

from the coating of the catalyst composition with coke and metals removed from the feedgenerally resultsfrom the coating of the catalyst composition with coke and metals removed from the feed

from the gradual accumulation of involatile coke species in the zeolite channelsmust therefore resultfrom the gradual accumulation of involatile coke species in the zeolite channels

in a low yieldsresultingin a low yields

from green oil formation or catalyst poisoning by a high CO concentrationresultingfrom green oil formation or catalyst poisoning by a high CO concentration

from a catalyst leaching phenomenonresultingfrom a catalyst leaching phenomenon

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