treating heavy oilsUS52981522 Jun 199229 Mar 1994Chevron Research And Technology CompanyProcessto preventcatalyst deactivation in
b ) Coking and fouling propensityresultsin catalyst deactivation
Rh segregation at the surface ... resulting from the volatilisation of Pt oxide at high temperatures after the oxidation of Rh and Pt(passive) may be caused bycatalyst deactivation
sulfur poisoning , in high concentrations(passive) caused bycatalyst deactivation
the main pollutantsleadingto catalyst deactivation
most catalyst lifetimes ... side reactionsleadto catalyst deactivation
In usual commercial use , these catalysts become fouled with metal contaminants and coke formationleadingto catalyst deactivation
that dehydration processes are too fast compared to H2 formation reactions at higher temperaturesleadingto catalyst deactivation
from coke deposition on the catalyst surfacesresultingfrom coke deposition on the catalyst surfaces
to higher conversion and longer operating timeleadingto higher conversion and longer operating time
from polyalkylation of aromatics ... perhaps with a minor contribution from oligomerization , especially where the propylene concentration is quite largeresultedfrom polyalkylation of aromatics ... perhaps with a minor contribution from oligomerization , especially where the propylene concentration is quite large
from use in eliminating oxides of nitrogen from gases EP0071397B1 ( enresultingfrom use in eliminating oxides of nitrogen from gases EP0071397B1 ( en
declining reaction rates and higher reactor occupancy with an increasing number of catalyst recycleswill causedeclining reaction rates and higher reactor occupancy with an increasing number of catalyst recycles
by performing the process in two stepscan be preventedby performing the process in two steps
from the decomposition of zinc titanates , which are active componentsresultedfrom the decomposition of zinc titanates , which are active components
to the termination of CNT growthleadsto the termination of CNT growth
to loss of stabilityleadto loss of stability
A decreasing activity as a function of time on stream at constant operating conditions(passive) is then caused byA decreasing activity as a function of time on stream at constant operating conditions
from carbon laydownresultingfrom carbon laydown
from steaming during regenerationresultingfrom steaming during regeneration
to the reduction of byproduct reactionsleadsto the reduction of byproduct reactions
further accumulation of carbon along the bedpreventsfurther accumulation of carbon along the bed
by tuning the ligand / Rh ratiocould be preventedby tuning the ligand / Rh ratio
to the loss of activity , XRD , TEM and thermogravimetry and differential thermogravimetryleadingto the loss of activity , XRD , TEM and thermogravimetry and differential thermogravimetry
4 , 7 , 8leads4 , 7 , 8
in a short catalyst lifetimeresultsin a short catalyst lifetime
to catalyst inhibition and deactivationleadto catalyst inhibition and deactivation
incomplete conversions in some cases and therefore no unique set of reaction conditions with broad scope could be identifiedcausedincomplete conversions in some cases and therefore no unique set of reaction conditions with broad scope could be identified
from the differing treatment as shown in EXAMPLE 5resultingfrom the differing treatment as shown in EXAMPLE 5
from the deposition of coke within the zeolite pores , which restricted access of the reactants to the BrCnsted acid sitesresultedfrom the deposition of coke within the zeolite pores , which restricted access of the reactants to the BrCnsted acid sites
to useful catalyst lifetimes on the order of only several hoursleadingto useful catalyst lifetimes on the order of only several hours
in little product yielddeviationresultingin little product yielddeviation
from a strong but slow chemical interaction between the Mn - O bond and sulfur dioxideresultedfrom a strong but slow chemical interaction between the Mn - O bond and sulfur dioxide
to the moving of the operating pointleadsto the moving of the operating point
from destruction of at least one of the two essential components of the catalyst described abovepresumably resultsfrom destruction of at least one of the two essential components of the catalyst described above
in increased catalyst usage and/or less effective hydrogenationresultingin increased catalyst usage and/or less effective hydrogenation
in little product yield deviationresultingin little product yield deviation
in a decrease of yield of p - xylene with time on stream as shown in Tables 1 - 7resultedin a decrease of yield of p - xylene with time on stream as shown in Tables 1 - 7
The base line experiments at(passive) is caused byThe base line experiments at
to lesser amount of reaction over the bedcontributedto lesser amount of reaction over the bed
from the coating of the catalyst composition with coke and metals removed from the feedgenerally resultsfrom the coating of the catalyst composition with coke and metals removed from the feed
from the gradual accumulation of involatile coke species in the zeolite channelsmust therefore resultfrom the gradual accumulation of involatile coke species in the zeolite channels
in a low yieldsresultingin a low yields
from green oil formation or catalyst poisoning by a high CO concentrationresultingfrom green oil formation or catalyst poisoning by a high CO concentration
from a catalyst leaching phenomenonresultingfrom a catalyst leaching phenomenon